By Pedro J. Pérez (Ed.),Pedro J. Pérez
Over the previous decade, a lot study attempt has been dedicated to the layout and synthesis of latest reagents and catalysts which may impression carbon-hydrogen bond activation, usually as a result of the prospect that C−H activation may well allow the conversion of inexpensive and ample alkanes into necessary functionalized natural compounds.
Alkane C-H Activation by way of Single-Site steel Catalysis provides the present cutting-edge improvement within the catalytic platforms for the catalytic trans-formations of alkanes below homogeneous stipulations. bankruptcy 1 bargains a entire precis of the most discoveries learned to date. bankruptcy 2 reports the so-called electrophilic activation, initiated through Shulpín within the past due 60s, and the bottom for the Catalytica system. bankruptcy three examines the catalytic borylation of alkanes, stumbled on by way of Hartwig, while bankruptcy four offers an up-to-date imaginative and prescient of the alkane dehydrogenation response. bankruptcy five covers the oxygenation of C-H bonds, a box of huge curiosity with bioinorganic im-plications, and at last bankruptcy 6 offers the functionalization of alkane C-H bonds by way of carbene or nitrene insertion.
The background of C-H bond activation, and the present study defined during this e-book, spotlight the present learn and current the reader with an outlook of this box which remains to be explored by way of an more and more visionary and enthusiastic staff of natural, organometallic, organic and actual chemists.
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Alkane C-H Activation by Single-Site Metal Catalysis: 38 (Catalysis by Metal Complexes) by Pedro J. Pérez (Ed.),Pedro J. Pérez